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Comparison of lead-free Surface treatment Technology
Posted: May 14, 2022 By: Bonnie

Comparison of lead free surface treatment of PCB


Advantages Disadvantages

Pb-free HASL

Good weldability: good preservation
The amount of solder paste used is relatively small

Easily appears tin beads.
OSP Low cost, smooth
Suitable for larger factories
It is easy to oxidize and the PC board can not be measured directly;
The use of solder paste is relatively increased.
ENIG It has flatness and good conductivity
It is easy to oxidize and the use of solder paste is relatively increased.
Electrolytic Ni/Au It has flatness;Low electrical resistance
High cost; If it is too thin, the gold is easy to catalyze and oxidize, and the use of solder paste is relatively increased.
I-Ag It has flatness;Low electrical resistance
It is easy to oxidize and dilute without Tin, and the strength of solder is poor,and the use of solder paste is relatively increased.
I-Sn It has flatness
The solder-ability decreases and the solder strength is poor,and the use of solder paste is relatively increased.


Lead free tin spraying advantages of tin, silver, copper and nickel


1) Tin spraying processing temperature is low (235-255 ℃), there will be no impact on the plate
2) The solder paste and solder rod (tin, silver and copper) produced by spraying tin material and PCBA are the same series of lead-free solder, so it has the best comprehensive performance, and there will be no brittle joint due to different melting points, resulting in dissolution stripping phenomenon.
3) The surface of solder joint is bright
4) The solder joint is not easy to oxidize and has a long storage life.
5) The thickness of tin spray is 40-100um, which can save the amount of solder paste used in the later stage. (the price of solder paste is 4 times that of tin bar)
6) It is easy to accept the processing habits of the engineers in the later stage of the process by continuing the process technology with lead tin spray.
7) The total cost (tin spray + reflow + wave soldering) is the lowest
8) Before the back welding + wave welding process, the inferior PC board can be screened in advance.
9) Mature technology

Lead free tin spraying

Types and analysis of lead free tin spray

Solder composition
Sn-Cu Sn-Cu-Ni-X
Sn-Au-Cu
Sn-Au-Cu-Ni
Processing price
1(250) 1.4(300) 2(350) 2(350)
Temperature (℃)
265-275 265-275 260-270 245-260
Back processing (wave soldering)
Not easy
Not easy
Easy Easy
Back processing (back peak welding)
Not easy
Not easy
Easy
Easy
Oxidation (preservation)
3(fast) 1 2 1(slow)
Brightness comparison
4(foggy) 2 3 1(bright)
Heat resistance
Bad(high temperature) Bad(high temperature)
Good Good
Counter explosion plate& ink heat resistance
4(high) 3 2 1(low)
Recommended

High temperature processing

Low temperature processing

Introduction to horizontal tin spraying

As one of the most common surface coating forms of PCB surface treatment, tin spraying smobc & Hal is widely used in the production of circuit boards. The quality of tin spraying directly affects the quality and solderability of soldering in subsequent production; Therefore, the quality of tin spraying has become a key point in the quality control of PCB manufacturers; there are two kinds of tin spraying: vertical tin spraying and horizontal tin spraying. The main functions of tin spraying are as follows
(1) prevent the oxidation of bare copper surface
2) keep the solder-ability;

Other methods of surface treatment are: hot melt, organic protective film OSP, chemical tin, chemical silver, chemical nickel gold, nickel plating gold, etc;


The main disadvantages of vertical tin spraying are as follows:
(1) uneven heating up and down of the board, last in first out, easy to appear the defect of plate bending and warping.
The thickness of the solder pad is not easy to stick due to the effect of hot air on the surface of the solder pad.
(3) the contact time between the solder pad on bare copper and the hole wall and solder is longer, generally more than 6 seconds. The copper solubility increases rapidly in the soldering furnace. The increase of copper content will directly affect the solder-ability of the pad, because the thickness of IMC alloy layer is too thick, which greatly shortens the shelf life of the board.


horizontal tin spraying


Compared with vertical tin spraying, horizontal tin spraying has the following advantages
(1) the contact time between molten tin and bare copper is short, about 2 seconds, the thickness of IMC is thin and the storage life is longer
(2) the time of tin dipping was short, wet time, about 1 second
(3) the board is heated evenly, the mechanical properties are good, and the board warping is less


The technological process of horizontal tin spraying is as follows
Pre cleaning treatment -- preheating --- flux coating --- horizontal tin spraying --- hot air knife tin scraping --- cooling --- post cleaning treatment


Do you have any questions about the above-mentioned? Contact us now, we will reply to you soon.
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